UNIVERSITY PARK, Pa. — When the Paleocene ended and the Eocene began nearly 56 million years ago, Earth’s atmospheric carbon dioxide levels ranged between 1,400 and 4,000 parts per million (ppm). These carbon dioxide levels gave rise to sauna-like conditions across the planet, which scientists can now measure using tiny minerals called siderites.
“I’ve been obsessed with siderites since I started my postdoctoral studies more than 20 years ago,” said Timothy White, research professor in Penn State’s Earth and Environmental Systems Institute. “The minerals only form in wetland soils under the right conditions — it has to be totally saturated, and the soils cannot be frozen. Siderites are not well described in geologic literature, but I noticed that when they do appear, it’s at very discreet intervals and in really warm greenhouse episodes.”
White and researchers from ETH Zurich and CASP in Cambridge, U.K., used siderite minerals to reconstruct the climate at the Paleocene-Eocene boundary. The siderites, provided by White, came from 13 different sites in the northern hemisphere and cover a broad range of geographical latitudes from the tropics to the Arctic.
The researchers found that the mean annual air temperature at the equator where Colombia lies today was around 106 Fahrenheit. Farther north in Arctic Siberia, the average summer temperature was 73 F. They also discovered that the tropics and higher latitudes would have had very high atmospheric humidity levels. They report their findings in a recent issue of Nature Geoscience.
“This is the first tropical continental temperature estimate on land, and it agrees with the only other dataset out there that shows the tropical paleoclimate temperature of the ocean surface at 38 Celsius (104 F),” said Joep van Dijk, who completed the research for his doctoral dissertation at ETH Zurich. Van Dijk was co-advised by Stefano Bernasconi, ETH Zurich, and White.
The siderite that the scientists studied formed in oxygen-free soil environments that developed under dense vegetation in swamps, which were abundant along the hot and humid coastlines in the Paleocene and Eocene. The mineral is composed of iron, carbon and oxygen atoms. As siderite crystals grow, the temperature of the soil influences which carbon and oxygen isotopes become embedded in the crystal lattice.
The researchers used a new method called clumped isotope thermometry to measure the temperatures and intensity of precipitation at the time the crystals formed. The method enabled them to determine the concentration of carbonate molecules in the siderite, which contain the heavy oxygen-18 and carbon-13 isotopes. Warmer soils mean that fewer molecules in the crystals contain both rare isotopes. Based on this concentration, the researchers were able to determine the temperature of the soil and, in turn, the mean air temperature.