UNIVERSITY PARK, Pa. — Collin Smyth shined with a $500 first place finish for his poster titled “Single-Pass Flow-Through Corrosion of Calcium Aluminosilicate Glass Powder” at the College of Earth and Mineral Sciences’ (EMS) fifth annual Undergraduate Poster Exhibition held on Nov. 30, but the path to success was months in the making.
Smyth, a senior majoring in materials science and engineering, illustrated his research on the types of glass best suited for the long-term storage of nuclear waste in glass. Specifically, he examined the composition dependence of the corrosion of glass, with applications in nuclear waste glass after vitrification. Vitrification is a process where nuclear waste is mixed with molten glass-forming chemicals and the nuclear waste is immobilized in the glass after it solidifies in canisters.
He spent the summer conducting the research with his adviser, Carlo Pantano, distinguished professor of materials science and engineering, which he said may have given him an edge over his competitors.
“All the data I presented came from the work I did over the summer so I already had a good level of understanding of the research since I’ve done so many experiments,” said Smyth. “I’ve had some things fail and go wrong, so I really understand every step of the experiment I’m doing, and that helps me better understand my results.”
Smyth researched three components found in glass: calcium oxide, alumina and silica. Nuclear waste glass can have about two dozen components, but his research focused on gaining empirical data on those three components.
Smyth passed water over powder-sized pieces of the glass for 18 days and found that higher silicon content led to a more stable glass that doesn’t as easily dissolve or corrode. Dissolution is an issue because that could potentially release the radioactive waste to the environment.
“When testing the 50 percent silica glass, the dissolution rate was about three times as high as the higher-percent silica samples, and the 40 percent silica was about four times as high,” said Smyth. “So, higher silica content will mean more corrosive-resistant storage for nuclear waste.”
“Glass corrosion has a lot of applications,” said Smyth. “People need to know about glass corrosion for thin films, biomaterials and nuclear waste, so nuclear waste is kind of the main motivation here but the results can be applied to other situations. The knowledge gained — because this is empirical data — can be used to determine the compositional effects of all glass corrosion.”
Also earning honors at the exhibition, were: